Select your calendar on the left-hand side of iPhoto and then head to the File menu and select Print. A new screen will pop up with a preview and some settings to alter.
You can flick through each page of the calendar here and also hit Print for a first (draft) copy of the calendar. Click Show Details to see more printing options.
Depending on your printer you will be able to use this drop down to go in and tweak all kinds of printing options. The most important are kept in the Layout section where you can add double-sided printing.
If you wish to save your calendar use this drop-down menu to select Save as PDF and then a location. You will then be able to take these files to a local printing shop to have the calendar made and bound.
Click Image to Enlarge:
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